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GAF, Timberline HDZ Shingles, Professional Use-10/01/2019
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Article
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Roof asphalt shinglesStructure such as solid, liquid, aerosol etc.
Form: solidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 20241 Campus Drive
Parsippany NJ 07054
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Chemical of Concern (CoC)
Chemical of Concern(CoC)Calcium carbonate (Limestone) 001317-65-3 25.0-45.0 No Asphalt, oxidized 064742-93-4 10.0-30.0 Yes 
CoC List
Quartz 014808-60-7 0-10.0 Yes CoC List
Fiberousglass 065997-17-3 1.0-3.0 Yes CoC List
Titanium dioxide 013463-67-7 0-4.0 Yes CoC List
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :October 01, 2019 -
Warnings
Hazard Statements
As defined in the OSHA Hazard Communication Standard, 29 CFR 1910.1200, the products listed below are considered articles and do not require an SDS.
Precautionary statements
General
None.
Prevention
None.
Response
None.
Storage.
None.
Disposal
None. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
None.
Potential Health Effects
Eye Contact: May cause irritation to the eyes.
Skin Contact: May cause irritation to the skin if dust is generated.
Inhalation: May cause irritation to the respiratory tract.
Ingestion: This product is not intended to be ingested. If ingested, it may cause temporary irritation to the gastrointestinal (digestive) tract. -
Chronic health effects
From SDS:
Studies in humans have found that exposure to respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs. Silicosis is a serious and irreversible disease; it may be progressive even after exposure has ceased; it can lead to disability and death. Human studies also have found that silicosis is a risk factor for tuberculosis, and that occupational exposure to respirable crystalline silica is associated with chronic obstructive pulmonary disease, including bronchitis and emphysema. Some studies show excess numbers of cases of scleroderma, connective tissue disorders, lupus, rheumatoid arthritis, chronic kidney diseases and end-stage kidney disease in workers exposed to respirable crystalline silica. -
Carcinogenicity
IARC has determined that occupational exposure to oxidized asphalt and its emissions is probably carcinogenic to humans (Group 2A). IARC concluded that available data from cancer studies in humans points to an association between exposures to oxidized asphalts during roofing and lung cancer and tumors in the upper aero-digestive tract. In addition, IARC found sufficient evidence of carcinogenicity in experimental animals for extracts and fume condensates of oxidized asphalts.
NIOSH has concluded that the collective data from human, animal, genotoxicity and exposure studies provide sufficient evidence that roofing asphalt fumes are a potential occupational carcinogen.
Occupational exposure to respirable crystalline silica is classified as a known carcinogen in humans. IARC has determined that respirable crystalline silica is carcinogenic to humans (Group 1), based on findings of sufficient evidence of carcinogenicity in both humans and experimental animals. NTP has classified respirable crystalline silica as a known human carcinogen based on sufficient evidence of carcinogenicity from studies in humans indicating a causal relationship between exposure to respirable crystalline silica and increased lung cancer rates in workers exposed to crystalline silica dust. NIOSH has determined that respirable crystalline silica is a potential occupational carcinogen.
IARC has determined that occupational exposure to Titanium Dioxide is possibly carcinogenic to humans (Group 2B). IARC concluded lung tumors were observed in rats following high dose exposure by inhalation and in female rats exposed by intra-tracheal instillation. Other studies have shown no tumors in rats following inhalation exposure and no tumors in mice or rats following oral exposure.
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Handling information
No specific handling or storage requirements.
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Disposal information
This product, as supplied, is not regulated as a hazardous waste by the U.S. Environmental Protection Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. Comply with state and local regulations for disposal.
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California Prop. 65 Warning
This product contains silica and titanium dioxide, chemicals known to the State of California to cause cancer.
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First Aid
Eye Contact: Hold eyelids open and wash with gentle stream of water for at least 15 minutes preferably at eyewash fountain.Skin Contact: Wash affected area thoroughly with soap and water.Inhalation: Remove to fresh uncontaminated air.Ingestion: Not expected to be ingested.
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UN Global Harmonization Classification